Louis Brus Wins 2005 American Chemical Society Materials Prize
It has been announced that Louis Brus, MRSEC Associate Director and Professor of Chemistry and Chemical Engineering, will be awarded the 2005 American Chemical Society (ACS) Chemistry of Materials Prize, sponsored by DuPont. The award recognizes research in establishing the field of semiconductor nanocrystals, which has applications that range from working as luminescent labels for studying biological systems to serving as effective components of medical diagnostic tools. Earlier in 2004, Brus was elected to the National Academy of Sciences, and he will be named the Samuel Latham Mitchill Professor of Chemistry.
Nick Turro and Colin Nuckolls Win 2004 Mayor Awards
William P. Schweitzer Professor of Chemistry Nicholas Turro was awarded the New York Mayor's Medal for Excellence in Physical Sciences. Colin Nuckolls, Associate Professor in the field of Organic Materials Chemistry, received the Mayor's Medal for Excellence in Science for a Young Investigator. Both are Columbia University MRSEC principal investigators.
Louis Brus is Elected to the National Academy of Sciences in 2004
Louis Brus, MRSEC Associate Director, Professor of Chemistry and Chemical Engineering and Thomas A. Edison Professor of Chemistry, has been elected to National Academy of Sciences.
Brus is one of the founders of a new branch of solid state physics and chemistry: inorganic nanostructures. He has pioneered the study of physical, electronic and chemical properties of semiconductor nanocrystals as a function of their size.
Brus was one of five Columbia University professors elected to the prestigious National Academy of Sciences. The announcement came during the Academy's 141 st annual meeting on April 20, 2004. A total of 72 new U.S. members were named, along with 18 foreign associates from 13 countries.
Nick Turro Wins the 2004 Pimentel Award in Chemical Education by the American Chemical Society
Nicholas Turro, William P. Schweitzer Professor of Chemistry, received the 2004 George C. Pimentel Award in Chemical Education by the American Chemical Society for his outstanding contributions to chemical education. He was presented with a certificate and $5,000 at the American Chemical Society's annual meeting in March, 2004. The symposium "Building Bridges to Understanding Chemistry through Innovation in Teaching and Education" was held in Turro's honor at this ACS Meeting.
MRSEC Congratulates Silverstein for Receiving the Mayor's Award
Dr.
Samuel Silverstein, founder and director of the Summer Research
Program(SRP) for High School Science Teachers, received the New
York City Mayor's Award for Public Understanding of Science on
October 8, 2003 for his work with the Summer Research Program.
SRP has placed four teachers in the MRSEC Research for Teachers(RET)
program each summer, and has co-sponsored them, making our MRSEC
RET program a great success. We congratulate Dr. Silverstein for
his wonderful work. (more
information)
Columbia
University MRSEC, IBM and The University of New Orleans Announce
First 3-D Assembly of Magnetic and Semiconducting Nanoparticles
Yorktown
Heights, NY, June 25, 2003 - Scientists from the Columbia University
MRSEC, IBM and the University of New Orleans today announced a
new, three-dimensional designer material assembled from two different
types of particles only billionths of a meter across.
In
the June 26 issue of the scientific journal Nature, the team describes
the precision chemistry methods developed to tune the particles'
sizes in increments of less than one nanometer and to tailor the
experimental conditions so the particles would assemble themselves
into repeating 3-D patterns.
Designing
new materials with otherwise unattainable properties, sometimes
referred to as "metamaterials," is one of the promises
of nanotechnology. Two-dimensional patterns had previously been
created from gold nanoparticles of different sizes and mixtures
of gold and silver. Extending this concept to three dimensions
with more diverse types of materials demonstrates the ability
to bring more materials together than previously realized.
"What
excites us the most is that this is a modular assembly method
that will let us bring almost any materials together," said
Christopher Murray, manager of nanoscale materials and devices
at IBM Research. "We've demonstrated the ability to bring
together complementary materials with an eye to creating materials
with interesting custom properties."
Murray
worked with Stephen O'Brien, assistant professor of applied physics
and applied mathematics at Columbia University; Franz Redl, a
postdoctoral researcher affiliated with both Columbia and IBM;
and Kyung Sang Cho, a post-doctoral researcher affiliated with
IBM and supported by the Advanced Materials Research Institute
of the University of New Orleans. The work was supported in part
by the National Science Foundation, the independent agency that
supports basic research in all fields of science and engineering,
through the Center for Nanostructured Materials at Columbia University
and by the Defense Advanced Research Agency (DARPA) through programs
on metamaterials and advanced thermoelectric materials.
The
scientists chose the materials for the experiments specifically
because of their dissimilar, yet complementary properties. Lead
selenide is a semiconductor that has applications in infrared
detectors and thermal imaging and can be tuned to be more sensitive
to specific infrared wavelengths. The other material, magnetic
iron oxide, is best known for its use in the coatings for certain
magnetic recording media.
The
combination of these nanoparticles may have novel magneto-optical
properties as well as properties key to the realization of quantum
computing. For example, it might be possible to modulate the material's
optical properties by applying an external magnetic field.
"This
was a demonstration of the ability to create such materials,"
O'Brien said. "Given the unique combination of these nanoscale
materials, we're in uncharted territory with respect to the properties,
which we will be working on in the future."
The
first step was to create the nanoparticles. The particle sizes
were calculated from the mathematical ideal of the structures
they wanted to create. In addition to fine-tuning the sizes, the
particles had to be very uniform, all within 5 percent of the
target size. They settled on iron oxide particles 11 nanometers
in diameter, which were created by Redl, and lead selenide particles
6 nanometers in diameter, created by Cho. There are approximately
60,000 atoms in one of the iron oxide nanoparticles and approximately
3,000 atoms in the lead selenide particles.
Next,
Redl assembled the nanoparticles - or more to the point, had the
particles assemble themselves-into three different repeating 3-D
patterns by tailoring the experimental conditions. Forming these
so-called "crystal structures," as opposed to random
mixtures of nanoparticles, is essential for the composite material
to exhibit consistent, predictable behaviors. Various other materials
are known to assemble spontaneously into these structures of close-packed
particles, but none has been made of two components in three dimensions
and at the length scales reported in the Nature paper.
"The
precise and energy-efficient self-assembly of matter into material
structures with properties that cannot be achieved otherwise is
an important goal for nanotechnology," said Mihail Roco,
NSF senior advisor for nanotechnology and chair of the National
Science and Technology Council's Subcommittee on Nanoscale Science
and Engineering. "This is just one way that nanotechnology
will help foster 'the next industrial revolution.'"
For
more details see related sites at Columbia
University, NSF,
and IBM
.
To
view a QuickTime Movie of the formation of the Bimodal Superlattice,
please click here

TEM
(left) of ordered array of 11 nm diameter maghemite (gamma-Fe2O3,
blue in schematic) and 6 nm diameter lead selenide (PbSe, red)
nanocrystals.
Nick
Turro Wins Major Columbia Teaching Award
NIcholas
Turro was awarded a Presidential Award for Excellence in Teaching
at Columbia University's 249th Commencemnt on May 21, 2003. This
prestigious award was awarded to only five faculty in the entire
university. George Flynn is a previous winner of this award. For
more details see Columbia
University Commencement.
Siu-Wai
Chan named a 2003 Guggenheim Fellow
Siu-Wai
Chan of the Columbia MRSEC and the Materials Science and Engineering
Program in the Department of Applied Physics and Applied Mathematics
has been named a 2003 Guggenheim Fellow to support her research
in new methods of preparing grain-boundary junctions of high temperature
superconductors. This year there are five new Guggenheim Fellows
at Columbia. Within the Columbia MRSEC, Prof. Chan investigates
the synthesis and properties of cerium oxide nanocrystals and
leads the high school visitation program. For more details see
Columbia
2003 Guggenheim Fellows.